Materials Science and Engineering
Laboratory name
Surface Science Laboratory   
Laboratory title
原子レベルで物質表面を構築・評価し新機能ナノ材料を開発
Laboratory overview
物質表面をナノオーダーで制御・評価し、ナノカーボンなどの新規物質を利用した新しいエネルギー 材料や環境材料の提案とその創製を目指す。具体的には電子・ 光学デバイス開発、燃料電池や太陽電池の電極材料等の高性能化、水フィルターなどの環境デバイス開発を進めている。
Main research themes
・カーボンナノ材料の合成と応用
・探針増強ラマン散乱分光法による材料評価
・次世代電池用高性能材料の開発
Individual research theme
  • Charaterization of Nanomaterials by Scanning Probe Microscopy

    吉村 雅満

    2017

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    Outcome:

    2024
    Bilayer graphene was synthesized using graphene oxide. Optimization of substrate structure, spin-coating conditions, and reduction conditions were explored. These surface structures were mainly analyzed using AFM.

    2023
    The frictional properties of conductive reduced graphene oxide were studied at an nano level. We found that the reduction decreases the oxygen functional groups, which in turn decreases the frictional force.

    2022
    In this research article, we report a method to fabricate conducting reduced graphene oxide (rGO) monolayer films reduced by methane plasma treatment within few minutes and the nanoscale characterization of local conductivity via conductive atomic force microscopy (C-AFM), realizing their applicability in highly transparent conducting electrodes.

  • Synthesis and evaluation of carbon materials

    吉村 雅満

    2017

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    Graphene is a monolayer of carbon with excellent electrical, thermal, and mechanical properties. However, since single-layer graphene is a zero-gap semiconductor, it must be processed into nanoribbons or other forms to create a gap. Carbon nanotubes, on the other hand, have a high aspect ratio and large surface area, making them suitable for battery electrodes.

  • Development of tip-enhanced Raman spectroscopy

    吉村 雅満

    2023

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    Outcome:

    2024
    We fabricated an enhanced probe with high reproducibility by coating the tip of the probe with silver and gold for plasmon excitation followed by FIB processing. Using this method, we succeeded in operating with the non-gap mode.

  • マイクロテクスチャー付き立体機械部品と新機能実現

    佐々木 実, 吉村 雅満, 粟野 博之, 武野 計二

    2022 - 現在

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    流線形の機械は流体抵抗を下げるマクロな構造であるが、表面にサメ肌状リブレット構造を用意すると、抵抗を更に低減できることが知られる。立体フォトリソグラフィ技術により、ミクロな意中の構造を広域に作れるようになった。各種マイクロテクスチャーを立体機械部品に作り、抵抗・摩擦低減、伝熱促進、放射制御、抗菌などの様々な新機能を省スペースで実現する。

    Outcome:

    2023
    マイクロテクスチャーを付与することで、抗菌パターンをロールに用意し、量産に適した圧延技術で部材に転写できた。赤外線サブ波長サイズのモスアイ構造を、凹レンズ金型に実現し反射防止構造を実現した。

    2024
    マイクロテクスチャーを付与することで、ステンレス部品からの赤外線の放射制御、銅部品の伝熱促進を確認した。また、熱交換機フィン用アルミ合金の薄板材にハスの葉状凹凸を付けることで撥水性を高めた。部品穴の内面に、摩擦を低減構造を実現した。また、シリコン部材に微細な柱アレイを創り、表面積を増やしつつ電池化学反応に伴う体積膨張を許容する電極を実現した。

  • Development of novel CNT composite electrodes for Li-ion battery and Li-ion capacitor

    原 正則

    2017

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    A novel electrode material for Li-ion battery (LIBs) and Li-ion capacitors (LICs) with high capacity and fast charge-discharge response is fabricated by using vertically aligned carbon nanotubes (CNTs) grown directly on a substrate electrode (carbon, Al or Cu) and its performance is evaluated. The CNTs-modified electrodes are synthesized by alcohol catalyzed chemical vapor deposition (AC-CVD). The performance of the CNT-modified electrodes are evaluated in aqueous solution or organic solvent.

    Outcome:

    2023
    To improve the capacity of VACNT-modified electrodes, Fe-Co ally catalysts were employed to the alchole catalyst chemical vaper deposition(AC-CVD) synthesis method. The CNT growth length increased up to 100 µm under the opimized growth condition, and the capacity was increased.

    2022
    To improve the charge-discharge capacity of vertically aligned carbon nanotube-modified electrodes, a multi-step synthesis method was developed to increase CNT growth length. The multi-step synthesis method provided 3 times longer CNTs, and the capacity was improved on the electrode modified with these CNTs.

  • Development of Electrocatalyst for Water Electrolyzer

    原 正則

    2017

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    For the development of polymer electrolyte water electrolyzer (PEWE), the synthesis of an anode catalyst with low overvoltage and high stability are important. We aim to develop iridium oxide and its alloy nanoparticle catalysts uniformly dispersed and supported on a highly conductive nanocarbon material.

    Outcome:

    2022
    Catalyts performance of IrO2 supported on B- and N-doped graphene was evaluated in a polymer electrolyte water electrolyzer. We clarified that IrO2/BN-doped graphene has high activity and durablity for the oxygen evolution reaction (OER).

  • Development of novel corbon-based electrodes for Na-ion battery cathode

    原 正則

    2023

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    To develop novel electrode materials for the cathodes in sodium-ion batteries, modified graphite and/or vartical-aligned carbon nanotubes (VA-CNTs) were synthesized and evaluated.

    Outcome:

    2023
    To improve the charge-discharge capacity of Na-ion battery cathodes, nitrogen-doped expanded graphite (EG) was synthesizedand evaluated.