Materials Science and Engineering
Laboratory name
Surface Science Laboratory   
Laboratory title
原子レベルで物質表面を構築・評価し新機能ナノ材料を開発
Laboratory overview
物質表面をナノオーダーで制御・評価し、ナノカーボンなどの新規物質を利用した新しいエネルギー 材料や環境材料の提案とその創製を目指す。具体的には電子・ 光学デバイス開発、燃料電池や太陽電池の電極材料の高性能化、水フィルターなどの環境デバイス開発を進めている。
Main research themes
・カーボンナノ材料の合成と応用
・探針増強ラマン散乱分光法による材料評価
・次世代電池用高性能電極材料の開発
Individual research theme
  • Charaterization of Nanomaterials by Scanning Probe Microscopy

    吉村 雅満

    2017

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    Outcome:

    2022
    In this research article, we report a method to fabricate conducting reduced graphene oxide (rGO) monolayer films reduced by methane plasma treatment within few minutes and the nanoscale characterization of local conductivity via conductive atomic force microscopy (C-AFM), realizing their applicability in highly transparent conducting electrodes.

  • Nanofabrication of nano carbon materials

    吉村 雅満

    2017

  • In-situ FTIR analysis of reactiono mechanism for water electrolysis

    原 正則

    2017

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    An electrochemical cell for infrared spectroscopy is desined and combined with a commercial infrared spectrometer to directly observe adsorbates on an electrode catalysts under various potential during the reaction.

    Outcome:

    2022
    An electrochemical infrared spectroscopy cell was fabricated and combined with an infrared spectrometer to measure the adsorption behavior of water molecules on a water electrolysis catalyst using an attenuated total reflection setup. The adsorption behavior of water molecules is depended on the support materials of catalysts.

  • Development of Ag nanoparticles-modified electrodes for CO2 reduction reaction

    原 正則

    2017

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    To develop Ag-modified electrocatalysts for the production of carbon monoxide by the electrochemical reduction of carbon dioxide, we elucidate the effects of Ag particle size and support conditions on the catalytic activity and durability to establish a synthesis method for highly active electrocatalysts.

    Outcome:

    2022
    Ag nanoparticles deposited on graphite electrodes were characterized for the electrochemical reduction reaction of carbon dioxide. The hydrogen evolution reaction, a side reaction of the carbon dioxide reduction reaction, causes desorption and aggregation of the Ag nanoparticles on the electrode.

  • Development of novel CNT composite electrodes for Li ion capacitor

    原 正則

    2017

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    A novel electrode material for Li-ion capacitors (LICs) with high capacity and fast charge-discharge response is fabricated by using vertically aligned carbon nanotubes (CNTs) grown directly on a substrate electrode (carbon, Al or Cu) and its performance is evaluated. The CNTs-modified electrodes are synthesized by alcohol catalyzed chemical vapor deposition (AC-CVD). The performance of the CNT-modified electrodes are evaluated in aqueous solution or organic solvent.

    Outcome:

    2022
    To improve the charge-discharge capacity of vertically aligned carbon nanotube-modified electrodes, a multi-step synthesis method was developed to increase CNT growth length. The multi-step synthesis method provided 3 times longer CNTs, and the capacity was improved on the electrode modified with these CNTs.

  • Development of Electrocatalyst for Water Electrolyzer

    原 正則

    2017

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    For the development of polymer electrolyte water electrolyzer (PEWE), the synthesis of an anode catalyst with low overvoltage and high stability are important. We aim to develop iridium oxide and its alloy nanoparticle catalysts uniformly dispersed and supported on a highly conductive nanocarbon material.

    Outcome:

    2022
    Catalyts performance of IrO2 supported on B- and N-doped graphene was evaluated in a polymer electrolyte water electrolyzer. We clarified that IrO2/BN-doped graphene has high activity and durablity for the oxygen evolution reaction (OER).

  • Synthesis and Evaluation of Anode Catalyst for Direct type Fuel Cell

    原 正則

    2017

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    To develop new anode electrocatalysts with highly active and selectivefor direct-type fuel cells using hydrogen carrier molecules (quinones, and glucose), the control of the elements of the nanoparticles, the size and surface structure of the catalyst, and the support material are important. We will develop and evaluate non-metallic catalysts suitable for hydrogen carrier molecules with aromatic ring structure.

    Outcome:

    2022
    The oxidation behavior of quinones used in direct-type fuel cells were evaluated on heteroatom-doped graphene catalysts. Boron-doped graphene has enhanced the catalytic activity for quinon-ased fuels

  • Synthesis of Novel Carbon Nanomaterials for Energy and sensing applications

    CHELLAMUTHU Jeganathan

    2017