Materials Science and Engineering
Laboratory name
Optical Functional Materials Laboratory   
Laboratory title
光を縦横無尽に制御するフォトニクス材料の研究
Laboratory overview
独自の材料設計指針に基づく新規な材料の開発を行い、独自技術を駆使して、高機能な材料に最適化した新規構造の微細構造光ファイバや微小共振器などを実現し、超広帯域光波制御およびフォトン創生を目指した高性能な光デバイスの開発を行っている。
Main research themes
・微細構造ファイバによるスーパーコンティニューム光生成
・高非線形ファイバによる光波制御
・新光活性イオン添加超広帯域光増幅・レーザ媒体の研究
・太陽光励起レーザ媒体の研究
Individual research theme
  • Supercontinuum governed by four-wave mixing, stimulated Raman scattering and cross-phase modulation in a birefringent tellurite fiber

    大石 泰丈, 鈴木 健伸

    2023

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    The supercontinuum (SC) generations in a birefringent TeO2-ZnO-Na2O-Bi2O3 (TZNB) tellurite microstructured optical fiber (BTMOF) have been demonstrated by pumping near the zero-dispersion wavelengths (ZDWs) with a tunable picosecond erbium-doped fiber laser.

    Outcome:

    2023
    When the pump is polarized parallel with the x-axis of the BTMOF, the SC broadening is governed by the four-wave mixing (FWM), stimulated Raman scattering (SRS) and cross-phase modulation (XPM). The FWM signal can be generated from 1538 to 1293 nm, and the idler can be emitted from 1597 to 1907 nm. Due to the high nonlinear property of the BTMOF, the XPM between the FWM signal and idler can be significantly amplified by the cascaded FWM effect. When the pump is polarized parallel with the y-axis of the BTMOF, the SC is broadened by the Stokes and anti-Stokes SRS. A broadest Stokes SRS band with a 10-dB bandwidth of 232 nm is generated by pumping at 1545 nm with an average pump power of 23.8 dBm. Potentially, widely tunable fiber lasers can be developed by exploring the FWM or SRS in highly nonlinear tellurite fibers with tailored dispersion profiles. The SC evolutions agree well with the numerical simulation.

  • Fabrication of an all-solid tellurite disordered optical rod for transverse localization of light

    大石 泰丈, 鈴木 健伸

    2023

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    Here, an all-solid tellurite optical rod with a disordered transverse refractive index profile was first fabricated to study the transverse localization of light.

    Outcome:

    2023
    In the late 1980s, it was proposed that an optical wave system in which the refractive index profile is random in the transverse plane but is invariant in the longitudinal direction supported the transverse localization of light. The transport of optical images using transverse localization of light and its potential applications in biological and medical imaging were demonstrated by using a polymer optical fiber. The experimental results showed that after a CW probe beam propagated in our 5-cm-long fabricated tellurite optical rod, the beam became localized. With the potential of tellurite glasses such as high nonlinearity, broad transmission window and the control of the refractive index difference, the performance of image transport through a tellurite disordered optical medium by transverse localization of light is expected to improve in the near future.

  • Fabrication of specialty optical fibers made of non-silica glass with high infrared transmittance and development of infrared image transmission technique through the optical fibers

    DE CLERMONT Jonathan(転出・退職), 鈴木 健伸, 大石 泰丈

    2023

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    Here, we realize infrared image transmission fibers using non-silica glasses.

    Outcome:

    2022
    In 2017, Stone et al. presented a silica multicore fiber with low index contrast image thanks to a special structure where same sized cores would never be neighbors, decreasing significantly the crosstalk between cores. More recently, Tuan et al. successfully created a long (10cm) all-solid tellurite glass disordered fiber (TDOF) with good image transportation at different wavelength (1.4 to 1.6µm). It is, though, known that the problem of disordered fiber is that image transmission can be distorted due to oversized clusters of fibers of same refractive indices. By coupling these two research, this work tries to find how to obtain better results compared to the TDOF previously reported in view of coupling efficiency or image resolution by using a honeycomb-like network with different sized neighbor cores with controlled randomness.

    2023
    Programmation for beam pattern evolution of a new fiber structure was made and early interesting results started to appear

  • Mid-infrared upconversion ghost imaging

    鈴木 健伸, DE CLERMONT Jonathan(転出・退職), 大石 泰丈

    2023

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    Mid-infrared upconversion is a technique that shows great potential for obtaining mid-infrared images using visible imaging sensors with outstanding sensitivity, response speed, and resolution. However, the visible light produced after conversion is often weak. To address this issue, this study proposes mid-infrared upconversion ghost imaging and evaluates its feasibility.

    Outcome:

    2023
    We conducted numerical simulations to explore the use of single-wavelength coherent light, single-wavelength incoherent light, and multi-wavelength incoherent light for mid-infrared upconversion ghost imaging. Our findings indicate that the resolution degradation caused by interference is lower when using single-wavelength incoherent light as compared to single-wavelength coherent light. However, distortion can occur when using a multi-wavelength light source due to the difference in magnification for each wavelength during upconversion. We also discovered that image deterioration can be reduced by using a compressed sensing method as an image reconstruction technique.

  • Development of tellurite glass optical fiber current sensor

    鈴木 健伸, DE CLERMONT Jonathan(転出・退職), 大石 泰丈

    2023

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    The importance of real-time current measurement is increasing with the rise in renewable energy generation. Optical fiber current sensors offer advantages such as remote measurement and no risk of electric shock. These sensors use materials with a high Verdet constant and a photoelastic coefficient of zero. Lead silicate glass has been the traditional material of choice, but its use is restricted due to regulations. The objective of this research is to find lead-free tellurite glass that can replace lead silicate glass.

    Outcome:

    2023
    By searching for the glass compositions in TeO2-ZnO-Li2O-Bi2O3 system glasses, we found glass compositions with lower photorealistic constant than that of conventional glass materials. We fabricated single-mode fibers using these glasses and confirmed the rotation of polarized light by magnetic fields.

  • Wavelength Dependence of the Nonlinear Refractive Index in Highly Nonlinear Glasses

    鈴木 健伸, 大石 泰丈

    2024

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    The aim of this study is to clarify the wavelength dependence of the nonlinear refractive index n_2 in chalcogenide and tellurite glasses. By systematically evaluating and comparing the nonlinear optical responses of these materials, the study seeks to provide guidelines for selecting suitable materials and optimizing excitation conditions at different wavelengths. In particular, the dispersion characteristics of n_2 will serve as fundamental data for achieving efficient wavelength conversion and supercontinuum generation in the mid-infrared region.

    Outcome:

    2024
    This study evaluated the nonlinear refractive index n_2 of Ge-As-Se chalcogenide glass (ChG) in the mid-infrared region using the Z-scan method. A threefold variation was observed across 2600–5000 nm, with a peak near 3500 nm. Simulations showed that supercontinuum (SC) generation bandwidth is maximized when pumped at this peak. These findings are valuable for mid-IR broadband light source design.

  • Exploration of Phase-Separated Glass Compositions for Transversely Disordered Optical Fibers for Infrared Image Transmission

    鈴木 健伸, 大石 泰丈

    2024

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    The objective of this study is to explore a new fabrication method for transversely disordered optical fibers (TDOFs), which are attracting attention for infrared image transmission, by utilizing phase-separated glass. Conventional TDOFs require complex and time-consuming fiber drawing processes. This study aims to simplify the fabrication process and achieve high-performance structures by harnessing phase separation phenomena. To this end, the research investigates glass compositions that exhibit phase separation and evaluates their thermal stability and crystallization behavior to identify materials suitable for fiber fabrication.

    Outcome:

    2024
    This study explores a new method for efficiently fabricating transversely disordered optical fibers (TDOFs) for infrared image transmission using phase-separated glass. Focusing on the TeO₂–B₂O₃–Ga₂O₃ system, phase separation was confirmed through striation patterns and compositional analysis. Adjusting the glass composition and melting conditions yielded thermally stable, phase-separated candidate.

  • loration of Low-Phonon Gallium Oxide Glass Compositions for Fiber Laser Applications

    鈴木 健伸, 大石 泰丈

    2024

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    The aim of this study is to explore glass compositions based on Ga₂O₃ that exhibit low phonon energy, are suitable for fiber fabrication, and are resistant to surface degradation caused by deliquescence. From the perspective of materials strategy, the study also aims to develop novel compositions that could serve as alternatives to fluoride and tellurite glasses, which contain scarce elements.

    Outcome:

    2024
    This study explored glass compositions for fiber laser applications using gallium oxide-based glasses. Additives were introduced to the cesium oxide and gallium oxide system to improve surface stability and thermal performance. The following compositions were found to be suitable: 30 mol% cesium oxide–65 mol% gallium oxide–5 mol% zinc oxide (CG5Zn), 30 mol% cesium oxide–65 mol% gallium oxide–5 mol% niobium pentoxide (CG5Nb), and 25 mol% cesium oxide–65 mol% gallium oxide–10 mol% lithium oxide (CG10Li). These glasses exhibited excellent thermal stability and low phonon energy, which are favorable for fiber drawing. Among them, CG10Li showed no visible surface degradation after storage under controlled indoor conditions. These compositions are promising alternatives to fluoride glasses and tellurite glasses as host materials for fiber lasers.

  • Wavelength conversion performance in a tellurite step-index optical fiber

    大石 泰丈, 鈴木 健伸

    2018 - 2022

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    Here, a tellurite step-index fiber with large core is fabricated to keep the zero-dispersion wavelength (ZDW) of the fundamental mode close to that of the material dispersion which is located in the near-infrared region.

    Outcome:

    2022
    Four-wave mixing (FWM) in optical fibers is promising for wavelength conversion in optical networks due to its ultrafast response and high bit rate transmission. To further improve the performance of FWM-based wavelength conversion such as its bandwidth and conversion efficiency, the low nonlinearity of silica fibers should be improved by using novel highly nonlinear soft-glass fibers such as lead-silicate, bismuth-oxide, tellurite and chalcogenide fibers. By using a femtosecond pulsed laser pumped in the vicinity of the ZDW, it is expected to broaden and extend the bandwidth of the FWM-based wavelength conversion towards the near-infrared window for potential applications. When the pump wavelength was tuned from 1647 to 1795 nm, the signal was tuned from 1550 to 1434 nm, and the idler was generated from 1757 to 2400 nm. A 17.5 dB maximum signal gain at 1550 nm and +1.1 dB idler conversion efficiency at 1757 nm were obtained. When the pump wavelength was 1795 nm, the signal and generated idler wavelengths were 1434 and 2400 nm, respectively. To the best of our knowledge, this is the first time to demonstrate a FWM-based wavelength conversion performance whose wavelength spacing is ~966 nm (from 1434 to 2400 nm) in a tellurite step index optical fiber as short as 1 m.

  • Highly nonlinear chalcogenide hybrid microstructured optical fibers with buffer layer and their potential performance of supercontinuum generation

    大石 泰丈, 鈴木 健伸

    2018 - 2022

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    We report here the design of a new chalcogenide hybrid microstructured optical fiber (HMOF) with a buffer layer around the core and its potential performance of tailoring chromatic dispersion and supercontinuum (SC) generation.

    Outcome:

    2022
    The new chalcogenide HMOF has an AsSe2 core. The refractive index difference ∆n between the AsSe2 core and cladding material is supposed to be 0.3. The fiber microstructure and the ∆n between the core and buffer materials are designed in order to obtain broad anomalous dispersion regimes with near-zero and flattened chromatic dispersion profiles for broadband SC generation. Moreover, the suppression of chromatic dispersion fluctuation caused by fiber transverse geometry variation is investigated. By using the proposed chalcogenide buffer-embed HMOFs, the calculation shows that near-zero and flattened anomalous chromatic dispersion regimes from 4.5 µm can be obtained. When the variation of fiber structure occurs for ±1, ±5 and ±10 %, the chromatic dispersion fluctuation can be greatly suppressed. In addition, the calculation shows that a broad SC spectrum from 2.5 to more than 16.0 μm can be obtained when a 0.9-cm-long section of the new chalcogenide buffer-embed HMOF is pumped at 5.0 μm by a femtosecond laser with 1-kW peak power.

  • Fabrication and supercontinuum generation in a tellurite hybrid microstructured optical fiber with near-zero and flattened chromatic dispersion control

    大石 泰丈, 鈴木 健伸

    2018 - 2023

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    Here, we show a broad and flattened SC spectrum with 5-dB spectral flatness over 1060 nm spectral bandwidth by using a 20-cm-long segment of the fabricated tellurite HMOF.

    Outcome:

    2023
    We succeeded in generating single-polarized mid-infrared SC light by controlling the wavelength dispersion and polarization-maintaining properties of a tellurite all-solid-state microstructured optical fiber with a flat core.

    2022
    Supercontinuum (SC) generation in optical fibers has been a topic of great interest because it can provide multiwavelength optical sources with high coherence and brightness which are useful for many potential applications such as wavelength division multiplexing transmission, optical frequency combs, spectroscopy and optical coherence tomography. However, SC spectra can also suffer from significant fluctuations in amplitude and it is important that the SC source is generated with low noise and with high spectral flatness. Recently, tellurite glasses have been employed for MOFs instead of silica glasses due to their high nonlinearity, wide transmission in the mid-IR region, low attenuation and high thermal stability. Several efforts have been devoted to obtain tellurite MOFs with flattened dispersion profiles because they can enhance the nonlinear spectral broadening and the spectral flatness of SC generation. But, they require very complex fiber structures which are difficult to be fabricated.
    In order to control chromatic dispersion profile of tellurite fibers in higher extent but simplify their fiber structure, our group proposed a tellurite hybrid microstructured optical fiber (HMOF). The fiber was successfully fabricated and its chromatic dispersion was tailored to be near-zero and flattened with three zero-dispersion wavelengths at 1270, 1973 and 3627 nm.

  • Suppressing chromatic dispersion fluctuation for broadband optical parametric gain in highly nonlinear tellurite microstructured optical fibers

    大石 泰丈, 鈴木 健伸

    2018 - 2022

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    In this work, we study the suppression of chromatic dispersion fluctuation and the performance of FOPA in a tellurite hybrid microstructured optical fiber (HMOF) with buffer layer by taking into account the variation in the core diameter and fiber transverse geometry.

    Outcome:

    2022
    Fiber-based optical parametric amplification (FOPA) is one of typical applications of four-wave-mixing (FWM) in highly nonlinear optical fibers which can transfer energy from one or two strong pump fields to a weak signal field and generate a new idler field. Since FOPA can provide broad gain bandwidths and high signal gain in many spectral bands where other types of optical amplifier cannot reach, it has been exploited for various applications such as signal amplification, wavelength conversion, phase-conjugation, slow and fast lights, optical signal processing and biomedical applications. However, high efficiency of FOPA performance is not easy to be obtained. It requires suitable pump sources, optical fibers with high nonlinearity and appropriate designs of chromatic dispersion which can satisfy the phase-matching condition. One of important technical issues for FOPA performance is that phase-matching condition for FWM in optical fibers is very sensitive to the fluctuation of chromatic dispersion which is caused by the fiber transverse geometry variation. A new fiber structure has been reported to suppress the chromatic dispersion fluctuation for silica fiber on the supposition that only the core diameter varies along the fiber length.
    It was shown that tellurite HMOF with buffer layer is more advantageous to suppress the chromatic dispersion fluctuation and to improve the FOPA signal gain and bandwidth than conventional tellurite HMOF without buffer layer. By optimizing the diameters and refractive indices of the core and buffer layer so as to effectively suppress the chromatic dispersion fluctuation, HMOF with buffer layer can be a promising medium to overcome the influence of fiber transverse geometry variation on the performance of FOPA.

  • Mid-infrared ghost imaging

    鈴木 健伸, DE CLERMONT Jonathan(転出・退職), 大石 泰丈

    2023

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    The purpose is to achieve high-quality imaging in the mid-infrared region without using expensive image sensors that suffer from low sensitivity and resolution. This aims to provide a cost-effective and high-performance measurement technique for applications that require mid-infrared wavelengths, such as medical diagnostics and gas sensing. Furthermore, by generating speckle patterns computationally and acquiring data using a single-pixel detector, the goal is to develop a novel imaging technique that does not rely on conventional cameras.

    Outcome:

    2024
    Mid-infrared imaging holds promise for applications in medicine and gas sensing. However, mid-infrared image sensors suffer from low resolution, low sensitivity, and high cost compared to those for visible and near-infrared light. To address these issues, computational ghost imaging (CGI), which does not require an image sensor, has been proposed. CGI reconstructs images using calculated speckle patterns instead of measuring them with a camera.

    In this study, a near-infrared ghost imaging system was constructed to evaluate the validity of CGI-generated speckle patterns and to investigate conditions for high-resolution imaging using a multimode fiber (MMF). Ghost imaging was performed by varying the MMF input position, CCD exposure time, and number of measurements. Image quality was assessed using SSIM.

    Shifting the input position from the center excited higher-order modes, resulting in finer speckles and improved resolution. The optimal exposure time was found to be 1500 μs, yielding speckle patterns closer to those actually projected. Under optimal conditions, the system achieved a maximum SSIM of 0.53, surpassing previous water-based approaches. Further resolution improvements are expected through post-processing.

    2023
    We conducted numerical simulations to explore the use of single-wavelength coherent light, single-wavelength incoherent light, and multi-wavelength incoherent light for mid-infrared upconversion ghost imaging. Our findings indicate that the resolution degradation caused by interference is lower when using single-wavelength incoherent light as compared to single-wavelength coherent light. However, distortion can occur when using a multi-wavelength light source due to the difference in magnification for each wavelength during upconversion. We also discovered that image deterioration can be reduced by using a compressed sensing method as an image reconstruction technique.